A one-dimensional (ID) polynuclear spin-crossover Fe-III complex, [Fe-III(acacen)(bpyp)](n)(BPh4)(n), showed a gradual and complete SC over a wide temperature range of ca. 250K between S = 5/2 and S = 1/2, where acacen = N,N'-bis(acetylacetonato)ethylenediamine, bpyp = 1,3-bis(4-pyridyl)propane, and BPh4- = tetraphenylborate. The single-crystal X-ray structures in the HS, LS, and midpoint between the HS and LS states were determined, and demonstrated that the SC may occur through the alternately arrayed HS- and LS-chains.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据