期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 71, 期 10, 页码 4028-4030出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo060369s
关键词
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Reaction of branched allylic sulfides with the N-Boc-oxaziridine 1 results in [2,3]-sigmatropic rearrangement of the intermediate allylic N-Boc-sulfimides with a high level of chirality transfer. The first example of formation of a quaternary stereocenter using this transformation is reported.
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