期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 64, 期 2, 页码 418-419出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2005.07.039
关键词
S-allyl-L-cysteine; deoxyallim; N-15 NMR; palladium(II)
类别
H-1-N-15 2D NMR data for S-allyl-L-cysteine (deoxyalliin) and for bis(S-allyl-L-cysteinate)palladium(II) complex are presented in this manuscript. Large upfield N-15 NMR shift of the amine nitrogen in the spectrum of the complex when compared to the spectrum of the ligand shows clearly coordination of S-allyl-L-cysteine, in the anion form, to palladium(II) through the NH2 group. (c) 2005 Elsevier B.V. All rights reserved.
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