期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 789, 期 1-3, 页码 128-132出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molstruc.2005.12.032
关键词
coordination polymer; Cd(II) complex; crystal structure; luminescence
A novel cadmium(H) coordination polymers, [Cd(bitmb)(2)center dot H2O], (1) (Hbitmb=4-(2-benzimidazolethiomethyl)benzoic acid) has been synthesized under hydrothermal conditions, and characterized by elemental analysis and IR spectra. X-ray diffraction analyses show that 1 is a 1D tubular structure, which is further assembled to 2D supramolecular network by H-bonding and pi-pi interactions. I is luminescent and displays an emissive maximum at 450 nm in the solid state at room temperature. (c) 2006 Elsevier B.V. All rights reserved.
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