期刊
CHEMICAL & PHARMACEUTICAL BULLETIN
卷 54, 期 6, 页码 788-794出版社
PHARMACEUTICAL SOC JAPAN
DOI: 10.1248/cpb.54.788
关键词
7-substituted indole; thallation; formyl group; tripeptide
7-Substituted (Cl, Br, I) indoles were synthesized by using thallation of N-formylindoline as a key reaction. Two precursor tripeptides for the right-hand segment of chloropeptin were synthesized by using (R)-7'-iodo and 7'-bromotryptophans derived from each 7-substituted indole (I, Br) obtained by the above procedure.
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