期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 691, 期 12, 页码 2713-2720出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2006.02.008
关键词
N-heterocyclic carbene; oxazoline; ruthenium; arene complex; chiral complexes
Reaction of a series of directly connected oxazoline-imidazolium salts with silver(l) oxide and subsequent transmetallation with [Ru(p-cymene)Cl-2](2) and anion exchange with KPF6 cleanly gave the corresponding 2-oxazolinyl-(N-mesityl)imidazolidene(chloro)ruthenium(II) half-sandwich complexes [RuCl(oxcarb)(p-cymene)]PF6, two derivatives of which were characterized by X-ray diffraction. Abstraction of the chloro ligand furnished the dicationic aqua complexes [Ru(H2O)(oxcarb)(p-cymene)](PF6)(2) which possess a similar coordination geometry. The syntheses were found to be highly diastereoselective, since only one diastereoisomer could be observed in all ruthenium complexes upon reaction of the chiral enantiopure oxazoline-imidazolium salts. Their potential as transfer hydrogenation and Lewis acid catalysts has been probed. (c) 2006 Elsevier B.V. All rights reserved.
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