Seasonal variation of the particle size distribution of n-alkanes and polycyclic aromatic hydrocarbons (PAHs) in urban aerosol of Guangzhou, China

Seasonal aerosol samples have been collected by Andersen Hi-Vol pumping system equipped with a five stage cascade impactor and a backup filter (size range: 10-7.2 mu m, 7.2-3.0 mu m, 3.0-1.5 mu m, 1.5-0.95 mu m, 0.95-0.49 mu m, <= 0.49 mu m) in the Liwan district, Guangzhou. n-Alkanes were measured using gas chromatography and PAHs were measured using gas chromatography/mass spectrometry analysis. The bimodal log-normal distributions of n-alkanes and semi-volatile PAHs were found, while for non-volatile PAHs that was unimodal, so much as the mode of semi-volatile PAHs was similar with that of the particles. The n-alkanes and PAHs were preferably associated with fine particles. C (max) (carbon number maximum) (C-22-C-26), CPI (carbon preference index) (1.12-1.21), U/R (unresolved to resolved components ratio) (7.42-10.7), wax% (0.9-3.12%) and the diagnostic ratios for PAHs revealed that vehicular emission was the major source of these organic compounds during the study periods, while the contribution of epicuticular waxes emitted by terrestrial plants was minor. CPI2 (values for petrogenic hydrocarbons), CPI3 (values for biogenic n-alkanes) and wax% revealed that the natural preferentially accumulated in the larger aerosol while the anthropogenic in the smaller. In addition, the different MMDs (mass median diameters) for n-alkanes and PAHs were observed in different seasons. The MMDs for n-alkanes and PAHs were higher in autumn/winter than those in spring/summer. The seasonal effect was related to the hydrocarbon content in the individual particulate fractions, showing a preferential association of n-alkanes and PAHs with larger particles in the autumn/winter season.