期刊
JOURNAL OF LUMINESCENCE
卷 118, 期 2, 页码 245-250出版社
ELSEVIER
DOI: 10.1016/j.jlumin.2005.08.020
关键词
diluted magnetic semiconductors; photoluminescence; ZnO
类别
We performed photoluminescence experiments on colloidal, Co2+-doped ZnO nanocrystals in order to study the electronic properties of Co2+ in a ZnO host. Room temperature measurements showed, next to the ZnO exciton and trap emission, an additional emission related to the Co2+ dopant. The spectral position and width of this emission does not depend on particle size or Co2+ concentration. At 8 K, a series of ZnO bulk phonon replicas appear on the Co2+-emission band. We conclude that Co2+ ions are strongly localized in the ZnO host, making the formation of a Co2+ d-band unlikely. Magnetic measurements revealed a paramagnetic behaviour. (c) 2005 Elsevier B.V. All rights reserved.
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