期刊
CHEMICAL PHYSICS LETTERS
卷 423, 期 4-6, 页码 276-281出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2006.03.065
关键词
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资金
- Engineering and Physical Sciences Research Council [GR/S96579/02, GR/S96579/01] Funding Source: researchfish
The sidebands observed in the magic angle spinning (MAS) NMR spectrum of a spin I = 1 H-2 nucleus may be very strongly broadened if motion is present in the solid. The broadening arises from interference between the line-narrowing effects of MAS and the dynamics-driven reorientation of the H-2 quadrupole tensor. Here, we show that this motional broadening is absent or much reduced in the corresponding double-quantum MAS NMR spectrum. This observation suggests a new approach to studying dynamics in solids and examples are drawn from H-2 MAS NMR of oxalic acid dihydrate, sodium tetrathionate dihydrate, and the synthetic polymer PMMA. (c) 2006 Elsevier B.V. All rights reserved.
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