期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 12, 期 17, 页码 4654-4661出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200600064
关键词
carbene ligands; metathesis; ruthenium
Various symmetrically and asymmetrically substituted N-heterocyclic carbene (NHC) ligands bearing aliphatic nitrogen-containing side groups have been synthesised. In our attempts to isolate the corresponding second-generation Grubbs catalysts, we were unsuccessful when using the symmetrical aliphatic NEC ligands. For the asymmetrical ligands bearing an aliphatic moiety on one side and an aromatic mesityl group on the other side, substitution of a phosphine ligand was achieved. The performance of a soformed series of Ru-based metathesis initiators has been evaluated for the ring-opening metathesis polymerisation (ROMP) of cycloocta-1,5-diene and the ring-closing metathesis (RCM) of diethyl diallylmalonate.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据