Iodine has been shown to be an efficient catalyst for the selective dihydroperoxidation of ketones with aqueous hydrogen peroxide. Ketones were directly converted to their corresponding gem-dihydroperoxides using a green oxidant (30% aq H2O2) and a simple catalyst ( iodine) under neutral conditions in acetonitrile. The yield of hydroperoxidation of various cyclic ketones was 60-98% including androstane- 3,17-dione, and acyclic ketones were converted with a similar efficiency.
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