期刊
ORGANIC LETTERS
卷 8, 期 13, 页码 2767-2770出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol060826r
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资金
- NCRR NIH HHS [S10 RR016640-01] Funding Source: Medline
- NIGMS NIH HHS [R01 GM035249-22, R01 GM035249, GM35249] Funding Source: Medline
We have successfully prepared potassium azidoalkyltrifluoroborates from the corresponding halogen compounds in 94 - 98% yields through a nucleophilic substitution reaction with NaN3. In the presence of various alkynes and Cu(I) as a catalyst, these azidotrifluoroborates easily formed 1,4-disubstituted organo-[1,2,3]-triazol-1-yl-trifluoroborates in 85-98% yields. This method was then developed into a facile one-pot synthesis for the preparation of various organo-[1,2,3]-triazol-1-yl-trifluoroborates using haloalkyltrifluoroborates as the starting materials.
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