期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 71, 期 13, 页码 5023-5026出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo060520y
关键词
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N-Boc-protected alkynylamines are converted into the corresponding alkylidene 2-oxazolidinones or 2-oxazinones under very mild reaction conditions in the presence of 1-5 mol% of a cationic Au(I) complex. The scope of the reaction is very general, providing the cyclic carbamates in high yield regardless of the substitution at nitrogen and alkyne terminus.
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