27Al NMR structural study on aluminum coordination state in bismuth doped silica glass

The aluminum coordination state in bismuth doped silica glass, which has new broad infrared emission at 1.3 mu m regions, was investigated by using Al-27 NMR, and it is demonstrated that 6-fold coordinated aluminum ions with corundum structure are dominant in bismuth doped silica glass until Bi2O3 concentrations of 1.0 mol% with Al2O3. The aluminum ion efficiently affects the creation of a Bi luminescent center at an intensity of Bi2O3 (1.0 mol%)-Al2O3 (2.3 mol%)-SiO2 (96.7 mol%); the sample is three orders of magnitude larger than the Bi2O3 (1.0 mol%-SiO2 (99.0 mol%) sample. Aluminum ions with corundum structure in silica glass have a very important role for the configuration of peculiar Bi luminescent centers. (c) 2006 Elsevier B.V. All rights reserved.