4.1 Article

Ketones in the catalytic three-component one-pot Kabachnik-Fields synthesis of α-amino phosphonates

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RUSSIAN CHEMICAL BULLETIN
卷 55, 期 7, 页码 1209-1214

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CONSULTANTS BUREAU/SPRINGER
DOI: 10.1007/s11172-006-0400-2

关键词

alpha-amino phosphonates; Kabachnik-Fields reaction; phthalocyanines; ketones; amines; phosphites; organophosphorus compounds

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Reactions of carbocyclic, heterocyclic, and steroidal ketones with benzylamine and diethyl phosphite in a catalytic three-component one-pot synthesis of alpha-amino phosphonates were studied. The activities of mono- and binuclear complexes of tetra(tert-butyl)phthalocyanines as catalysts for this process were compared.

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