期刊
CARBON
卷 44, 期 8, 页码 1572-1580出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2005.12.027
关键词
carbon nanofibers; chemical vapor deposition; transmission electron microscopy; microstructure
Carbon nanofibers were produced by the catalytic CVD process by the floating catalyst method, in semi-industrial systems at temperatures above 1350 K. Iron-derived carbon nanofibers Were produced from natural gas and xylene, using ferrocene as catalyst source, yielding a thickened submicron vapor grown carbon fibers with a core of multi-wall nanotubes. For the production of Ni derived nanofibers, natural gas was used as the carbon feedstock, and the Ni was added in a nickel compound solution. When no sulfur is used, only soot was obtained, but when sulfur is added to the reactive feedstock, a highly graphitic and very nice stacked-cup-type nanofibers with no free-CVD thickened layer were produced. TEM-EDS analysis confirms that this type of stacked-cup carbon nanofiber is produced only with a partially molten catalyst and methane as hydrocarbon source. In fact, very few fibers have either a particle tip at the end or trapped metal particle inside the wide hollow core of this type of produced carbon material. (C) 2006 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据