期刊
CONCEPTS IN MAGNETIC RESONANCE PART A
卷 28A, 期 4, 页码 249-269出版社
JOHN WILEY & SONS INC
DOI: 10.1002/cmr.a.20056
关键词
convection compensation; NMR diffusion and flow measurements; double-quantum filtering; apparent diffusion coefficient; homonuclear scalar couplings; excitation-sculpting water suppression
Many practical applications of diffusion NMR, ranging from biomedical to industrial, entail the measurement of low-concentration solutes in nondeuterated, compositionally complex systems. This article presents examples of robust, versatile diffusion experiments that can be used with nondeuterated solvents at nonambient temperatures. Specifically, three experiments are presented in detail: CONVEX, which combines excitation-sculpting solvent suppression with double-echo convection-compensating PGSE; DQDiff, which implements double-quantum filtered diffusion measurements in a convection-compensating mode; and applications of oscillating-gradient spin-echo (OGSE) to systems with homonuclear scalar couplings. These examples are based on the recent work by the authors and relate to a variety of systems, ranging from simple solutions to colloidal and polymeric systems. Besides the applied aspects, we review the general methodology used to treat the effects of diffusion and flow in NMR experiments, and apply this theory to derive the diffusion attenuation expression for each of the experiments presented. The article should be useful to beginners as well as advanced users of general NMR wishing to learn about diffusion measurements. (C) 2006 Wiley Periodicals, Inc.
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