期刊
ORGANIC LETTERS
卷 8, 期 14, 页码 3077-3079出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol061053+
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资金
- NCRR NIH HHS [P20 RR016480] Funding Source: Medline
[GRAPHICS] A recycle and reusable fluorous (S)-pyrrolidine sulfonamide organocatalyst has been developed for promoting highly enantio- and diastereoselective Michael addition reactions of ketones and aldehydes with nitroolefins in water. The organocatalyst is conveniently recovered from the reaction mixtures by fluorous solid-phase extraction and can be subsequently reused (up to six cycles) without a significant loss of catalytic activity and stereoselectivity.
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