期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 71, 期 14, 页码 5249-5253出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo060597m
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[GRAPHICS] The reaction of enynals 1, including o-(alkynyl) benzaldehydes, and carbonyl compounds 2, such as aldehydes and ketones, in the presence of a catalytic amount of AuBr3 in 1,4-dioxane at 100 degrees C gave the functionalized aromatic compounds 3 in high yields. Similarly, the AuBr3-catalyzed reactions of 1 with acetal compounds 5 afforded the corresponding aromatic compounds 3 in good yields. On the other hand, when the reaction was carried out in the presence of a catalytic amount of Cu(NTf2)(2) and 1 equiv of H2O in (CH2Cl)(2) at 100 degrees C, the decarbonylated naphthalene products 4 were obtained selectively over 3. Benzofused heteroaromatic compounds, such as indole derivatives 13 and benzofuran derivatives 15, were also synthesized by using the present benzannulation methodology.
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