期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2006, 期 14, 页码 3074-3078出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200600332
关键词
rearrangement; 1,3-diyne; 1,5-dien-3-yne; metal carbene; metallotropic [1,3]-shift
1,3-Diynes possessing propargylic heteroatom substituents provide functionalized 1,5-dien-3-ynes when catalyzed by platinum and gold. This rearrangement implies the involvement of metallotropic [1,3]-shift of the intermediate alkynyl metal carbene species. (c) Wiley-VCH Verlag GmbH & Co.
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