期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 254, 期 1-2, 页码 53-57出版社
ELSEVIER
DOI: 10.1016/j.molcata.2006.03.026
关键词
metathesis; ruthenium; isomerization; tandem reaction
Conversion of ruthenium carbene complexes to ruthenium hydride complexes by organometallic transformations in situ opens up interesting synthetic perspectives. In this account the use of Grubbs' catalyst to synthesize pent-4-enals selectively from diallyl- and allyl homoallyl ethers and scope and limitations of a Tandem RCM-isomerization sequence for the synthesis of cyclic enol ethers are discussed. (c) 2006 Elsevier B.V. All rights reserved.
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