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卷 8, 期 15, 页码 3159-3162出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol060697e
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资金
- NIDCR NIH HHS [DE13030] Funding Source: Medline
A polypseudorotaxane consisting of cucurbit[7]uril (CB[7])/N,N'-(3-phenylenebis(methylene) dipropargylamine (PMPA), [2] pseudorotaxane, and 2,6-O-dimethyl, beta-cyclodextrin (DM-beta-CD)/alpha,omega-bisazidopropylene glycol 400 [2]pseudorotaxane was synthesized using the click reaction. The polypseudorotaxane structure was maintained in aqueous solution over a wide range of pH values with the DM-beta-CD units contributing to increased solubilization of the polypseudorotaxane without dethreading. The pH-responsive movement of the CB[7] units in the polypseudorotaxane was also observed.
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