期刊
ACS APPLIED MATERIALS & INTERFACES
卷 7, 期 41, 页码 22907-22917出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b08875
关键词
shape sensitivity; palladium nanocubes; palladium nanoparticles; carbon@Fe3O4; K-4[Fe(CN)(6)]; {100} surface facets
资金
- UGC, New Delhi, India
- DST, New Delhi, India
- CSIR
Isolated chemical reactors were fabricated by integrating catalytically active sites (Pd) with magnetic functionality (Fe3O4) along with carbon while preserving the constituents functional properties to realize the structure-property relationship of Pd by comparing the catalytic activity of spherical Pd NPs with cubical Pd NPs for cyanation in aryl halides using K-4[Fe(CN)(6)] as a green cyanating agent to yield corresponding nitriles. The superior catalytic reactivity of the cubical Pd NPs is attributed to the larger number of {100} surface facets. The TEM images of reused catalyst shows the change in structure from cubical to spherical nanoparticles, attributed to the efficient leaching susceptibility of Pd {100} surface facets. The cubical Pd NPs on carbon@Fe3O4 is attractive in view of its high catalytic efficiency, easy synthesis, magnetic separability, environmental friendliness, high stability, gram scale applicability, and reusability.
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