期刊
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
卷 55, 期 3-4, 页码 197-218出版社
SPRINGER
DOI: 10.1007/s10847-006-9096-z
关键词
absorption properties; azocalixarene; complexation; extraction; thermal behaviours
Azocalixarenes, which have a conjugated chromophore azo (-N=N-) group in p-positions, are synthesized in one-pot procedures in satisfactory yields. Their structures in the solid and solution are elucidated by UV-vis, FTIR, H-1 and C-13 NMR spectroscopic methods as well as elemental analysis techniques. Some of them are complexed with metal ions (alkali, alkaline-earth and transition metal ions) under neutral conditions. A wide variety of applications is expected by the functionalization of the side arms. The selective liquid-liquid extraction of various alkali, alkaline-earth and transition metal cations from the aqueous phase to the organic phase is carried out by using azocalixarenes. Furthermore, the synthesized azocalixarenes are utilized for selective extraction of Fe3+ cations from the aqueous phase to the organic phase. The effects of varying pH and solvent upon the absorption ability of azocalixarenes substituted with electron-donating and electron-withdrawing groups at their o-, m-, p-positions are examined. The thermal behaviours of azocalixarenes containing upper rim functionalized groups are investigated by means of thermogravimetry (TG), differential thermal analysis (DTA) and differential thermogravimetry (DTG).
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