期刊
SYNTHETIC METALS
卷 156, 期 16-17, 页码 1102-1107出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.synthmet.2006.07.006
关键词
PEDOT; vapor phase polymerization; VPP-PEDOT; soft contact lamination; all-plastic solar cell; ultraviolet photoelectron spectroscopy
We demonstrate a prototype solar cell with a transparent polymer cathode, and indium-tin-oxide (ITO)/poly (3, 4-ethylene dioxythiophene)-poly (styrene sulphonate) (PEDOT:PSS) anode. As an active layer, thin film of a bulk heterojunction of polyfluorene copolymer poly[2,7-(9,9-dioctyl-fluorene)-alt-5,5-(4',7'-di-2thienyl-2',1'3'-benzothiadiazole)] (APFO-3) and an electron acceptor molecule [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM) (1:4 wt.) was sandwiched between the two transparent polymer electrodes. The cathode is another form of PEDOT formed by vapor phase polymerised PEDOT (VPP PEDOT) of conductivity 10(2)-10(3) S/cm. The cathode is supported on an elastomeric substrate, and forms a conformal contact to the APFO-3/PCBM blend. Transparent solar cells are useful for building multilayer and tandem solar cells. (c) 2006 Elsevier B.V. All rights reserved.
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