期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 179, 期 8, 页码 2602-2608出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2006.04.056
关键词
apatite; lanthanum silicate; X-ray diffraction; neutron diffraction; nuclear density spread
Crystalline structures of La9.33Si6O26 and La(9)AESi(6)O(26+delta) (AE = Ba, Sr and Ca) doped apatites-type lanthanum silicates were investigated by X-ray and neutron powder diffraction at room temperature. The results obtained after different models testing show that the apatite structure is best described using the P6(3) space group. The loss of the mirror symmetry perpendicular to the ionic conduction channel direction results from heterogeneous La3+/AE(2+) distribution of the sites so-called 4f. The Rietveld refinements do not show splitting of the conduction oxygen (0, 0, 1/4) site but rather a very large spread of the nuclear density associated to this site. This effect is more pronounced for the La(9)AESi(6)O(26+delta)-doped compounds. Large anisotropic thermal displacement parameters are also observed for the oxygens associated to the isolated [SiO4], suggesting a rotation of this tetrahedron around the Si site. Lastly, vacancies were also systematically observed in the lanthanum nine-coordinated sites. (c) 2006 Elsevier Inc. All rights reserved.
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