Electrochemical reaction of lithium with nanosized vanadium antimonate

Nanometric vanadium antimonate, VSbO(4), was prepared by mechanical milling from Sb(2)O(3) and V(2)O(5) and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Mossbauer spectroscopy (MS) and X-ray photoelectron spectroscopy (XPS) techniques. Its reactivity towards lithium was examined by testing Li/VSbO(4) Cells under galvanostatic and potentiostatic regimes. The amount of Li inserted was found to be consistent with a two-step process involving the reactions (i) VSbO(4) + 8 Li -> Sb + V + 4 Li(2)O and (ii) Sb + 3 Li -> Li(3)Sb, the former being virtually irreversible and the latter reversible as suggested by the shape of the anodic and cathodic curves. Ex situ XPS measurements of the discharged and charged electrode provided direct evidence of the formation of alloyed Sb and confirmed the results of the potentiostatic curves regarding the irreversible or reversible character of the previous reactions. The Li/VSbO(4) cell exhibited acceptable electrochemical performance, which surpassed that of other Sb-based compounds as the likely result of the formation of V and its associated enhanced electrode conductivity. (c) 2006 Elsevier Inc. All rights reserved.