期刊
CARBON
卷 44, 期 10, 页码 1994-2001出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2006.01.025
关键词
carbon composites; pyrolysis; dynamic mechanical thermal analysis; mechanical properties
A porous two-dimensional C/C composite was produced via the polymer pyrolysis route using phenolic resin as the matrix precursor and polyacrilonitrile- (PAN-) or pitch-based carbon fibres as reinforcement. The resulting C/C composites were then densified using a modified polysilane followed by pyrolysis to convert the polymer into silicon carbide, sealing the pores in the C/C composite. Aiming to increase the ceramic yield of the infiltrated polysilane and to reduce its volumetric shrinkage during pyrolysis the polymer's curing behaviour was modified by catalytic addition of 0.1% dicobaltoctacarbonyl [Co-2(CO)(8)]. The densification procedure is very efficient in sealing cracks in the C/C composite with SiC. The obtained carbon fibre reinforced C/SiC dual matrix composites were subjected to flexural tests and dynamic mechanical analysis. The flexural and visco-clastic properties of the composite are dominated by the strength of the fibre/matrix interface rather than by the fibre strength or modulus. A correlation between the mechanical loss factor (tan delta) and the fracture behaviour of the composite is suggested. (c) 2006 Elsevier Ltd. All rights reserved.
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