Room temperature synthesis and Li insertion into nanocrystalline rutile TiO2

Nanocrystalline rutile TiO2 is prepared at RT from acidic solution by sol-gel method using titanium tetraisopropoxide as precursor. Samples of varying crystallite sizes are prepared by post annealing the as synthesized rutile TiO2 at different temperatures. The absorption spectra of synthesized samples reveal a large blue shift (311 nm) vis a vis bulk rutile TiO2 (394 nm) indicating the nanocrystalline nature of the material. Electrochemical studies performed at RT show that one Li per formula unit is inserted into the nanocrystalline rutile TiO2. Variation in the voltage profiles is observed with respect to small changes in the crystallite sizes within the nanometric regime. (c) 2006 Elsevier B.V. All rights reserved.