Treatment of paper and pulp wastewater and removal of odorous compounds by a Fenton-like process at the pilot scale

A Fenton-like process, involving oxidation and coagulation, was evaluated for the removal of odorous compounds and treatment of a pulp and paper wastewater. The main parameters that govern the complex reactive system [pH and Fe(III) and hydrogen peroxide concentrations] were studied. Concentrations of Fe(III) between 100 and 1000 mg L-1 and of H2O2 between 0 and 2000 mg L-1 were chosen. The main mechanism for color removal was coagulation. The maximum COD, color and aromatic compound removals were 75, 98 and 95%, respectively, under optimal operating conditions ([Fe(III)] = 400 mg L-1; [H2O2] = 500- 1000 mg L-1; pH = 2.5;followed by coagulation at pH 5.0). The biodegradability of the wastewater treated increased from 0.4 to 0.7 under optimal conditions and no residual hydrogen peroxide was found after treatment. However, partially or non-oxidized compounds present in the treated wastewater presented higher acute toxicity to Artemia salina than the untreated wastewater. Based on the optimum conditions, pilot-scale experiments were conducted and revealed a high efficiency in relation to the mineralization of organic compounds. Terpenes [(1S)-alpha-pinene, beta-pinene, (1R)-alpha-pinene and limonene] were identified in the wastewater and were completely eliminated by the Fenton-like treatment. (c) 2006 Society of Chemical Industry.