期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 128, 期 30, 页码 9919-9925出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja062233h
关键词
-
The photochemical reaction of Sc3N@C-80 with 1,1,2,2-tetramesityl-1,2-disilirane affords the adduct as a bis-silylated product. The adduct was characterized by NMR spectroscopy and single-crystal X-ray structure analysis. The dynamic behavior of the disilirane moiety and the encapsulated Sc3N cluster were also investigated. The unique redox property of the adduct is reported by means of CV and DPV. Experimental results were confirmed by density functional calculations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据