Interaction of functional groups of gelatin and montmorillonite in nanocomposite

As an amphoteric polyelectrolyte, gelatin could intercalate into the galleries of montmorillonite (MMT). In this paper, sodium laurate/MMT composites and sodium laurate/dehydroxylated MMT composites were introduced as low molecular simulation to investigate the interaction functional groups of gelatin and MMT. The composites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectra (FTIR), thermogravimetric analysis (TGA) and C-13 nuclear magnetic resonance (C-13 NMR). Furthermore, the effect of interaction between gelatin and MMT on the mechanical properties of the composites was investigated. The results indicated that -COO-, not -COOH, in gelatin chains could interact strongly with the MMT sheets. The reactive sites on MMT were hydroxyl groups, which could interact with -COO- in gelatin chains by forming hydrogen bonds. The gelatin/MMT composites prepared in alkalic media have better mechanical properties due to stronger interaction. (c) 2006 Wiley Periodicals, Inc.