N-phenyl-3-substituted 5-pyrazolone derivatives as organic stabilizers for rigid poly(vinyl chloride) photodegradation

N-Phenyl-3-substituted 5-pyrazolone derivatives were investigated as organic photostabilizers for rigid poly(vinyl chloride) (PVC). Their stabilizing efficiency was evaluated by the determination of the weight loss of the polymer after irradiation for different periods and by the determination of the amount of gel formation as well as the intrinsic viscosity of the soluble fraction of the degraded polymer. Moreover, the efficiency was evaluated from the extent of the discoloration of the degraded polymer. This was attributed not only to the radical trapping potency of the pyrazolone derivatives, which intervened with the radical degradation species in the degradation process of PVC, but also to the blocking of the newly formed radical sites on the polymeric chains. Their stabilizing efficiencies were compared with those of phenyl salicylate and 2-hydroxy-4(octyloxy)phenyl benzophenone, industrially known UV absorbers. (c) 2006 Wiley Periodicals, Inc.