期刊
TETRAHEDRON LETTERS
卷 47, 期 33, 页码 5915-5917出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.06.041
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The preparation of a 12-membered ring macrolactone model of auriside that contains a pendant diene chain bearing a bromide was investigated employing two approaches. The first approach utilized an oxidative rearrangement of a tertiary allylic alcohol on a 12-membered ring. The second approach was based on a 1,4-methylation of an ynone followed by macrolactonization. (c) 2006 Elsevier Ltd. All rights reserved.
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