Blue sensitizers for solar cells: Natural dyes from Calafate and Jaboticaba

Blue-violet anthocyanins from Jaboticaba (Myrtus cauliflora Mart) and Calafate (Berberies buxifolia Lam) were employed as TiO2, dye-sensitizers. Solar cells sensitized by Jaboticaba extracts achieved up to J(SC) = 9.0 mA cm(-2), V-OC = 0.59 V, P-max = 1.9 MW cm(-2) and ff = 0.54, while for Calafate sensitized cells the values determined were up to J(SC) = 6.2 mA cm(-2), V-OC = 0.47 V, P-max = 1.1 MW cm(-2) and ff = 0.36. Other natural dyes were evaluated without significant photocurrent, demonstrating that only selected extracts are capable of converting sunlight in electricity. The results obtained with extracts of Jaboticaba and Calafate show a successful conversion of visible light into electricity by using natural dyes as wide band-gap semiconductor sensitizers in dye-sensitized solar cells. It also represents an environmentally friendly alternative for dye-sensitized solar cells with low cost production and an excellent system for educational purposes. (c) 2006 Elsevier B.V. All rights reserved.