期刊
SYNLETT
卷 -, 期 13, 页码 2071-2074出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-948198
关键词
aldehydes; allylations; organometallic reagents; regioselectivity; tin
A catalytic allyl-transfer reaction from tertiary homoallylic alcohols to aldehydes was achieved using dibutyltin oxide as a catalyst in toluene under reflux conditions. Various secondary homoallylic alcohols were prepared in high yield (up to 99%). When beta-alkylated tertiary homoallylic alcohols were used, branched products were exclusively obtained.
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