期刊
TETRAHEDRON
卷 62, 期 34, 页码 8054-8063出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.06.022
关键词
catalytic asymmetric synthesis; chiral building blocks; intramolecular cyclopropanation; total synthesis
A new asymmetric total synthesis of enantiopure (-)-methyl jasmonate is described. This synthesis was accomplished starting from the new enantiopure building block prepared via the catalytic asymmetric intramolecular cyclopropanation (IMCP) of the alpha-diazo-beta-keto 1-naphthyl sulfone, which was devised to give good selectivity both in the IMCP reaction and in the C-alkynylation of the intermediate required for the total synthesis of enantiopure (-)-methyl jasmonate. (c) 2006 Elsevier Ltd. All rights reserved.
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