期刊
TETRAHEDRON LETTERS
卷 47, 期 34, 页码 6057-6061出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.06.101
关键词
chemiluminescence; Cypridina bioluminescence; imidazopyrazinone; substituent effects; reaction mechanism
The chemiluminescence of 6-aryl-2-methylimidazo [1,2-a]pyrazin-3 (7 H) -ones (Cypridina luciferin analogues) in DMSO/ 1,1,3,3-tetramethylguanidine and in diglyme/acetate buffer was investigated. The results indicate that the reaction mechanism that produces a high chemiluminescence quantum yield involves a chemiexcitation process from a neutral dioxetanone intermediate possessing an electron-donating aryl group (sigma(Ar) <-0.6) to the singlet-excited state of neutral acetamidopyrazine. This result may be applied to the reaction mechanism for Cypridina (Vargula) bioluminescence. (c) 2006 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据