期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 795, 期 1-3, 页码 78-83出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molstruc.2006.02.019
关键词
water clusters; FTIR spectroscopy; matrix isolation; structure
The infrared spectra of water clusters trapped in argon and krypton matrices have been analyzed on the basis of recent quantum chemical calculations. Comparing the observed spectra with the band positions and intensities estimated by calculations for the water clusters, we have identified almost all bands observed in the bonded OH stretching region. In addition to the absorptions of the cyclic water trimer, tetramer, and pentamer, the present analysis reveals some infrared bands of the cage and book isomers of the water hexamer. For the cyclic pentamer, the second bonded OH stretching band is found to be absent or very weak, in contrast to the quantum chemical calculations. (c) 2006 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据