Synthesis and morphological evolution of CuGaS2 nanostructures via a polyol method

Using ethylene glycol as solvent and reductant, CuCl2 center dot 2H(2)O, (NH2)(2)CS and self-prepared GaCl3 as the starting materials, CuGaS2 nanostrucutures were synthesized on a large scale at 220 degrees C. Powder X-ray diffraction, transmission electron microscopy, field-emission scanning electron microscope, high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy were used to characterize the products. It demonstrated the evolution of the CuGaS2 particles from spherical assemblies to flowerlike morphology, over time, at 220 degrees C. Simultaneously, we elucidated the specific roles of reaction temperature, reaction time and solvent in the formation of the final CuCaS2 nanostructures. A possible formation mechanism of CuCaS2 nanostrucutures was also discussed. The room temperature photoluminescence spectrum showed blue-shift and an increase of intensity, with a decrease in the sizes of CuGaS2 particles.