4.8 Article

Amplification of enantiomeric concentrations under credible prebiotic conditions

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NATL ACAD SCIENCES
DOI: 10.1073/pnas.0605863103

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amino acids; crystallization; transamination

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Solutions with as little as 1% enantiomeric excess (ee) Of D- or L-phenylalanine are amplified to 90% ee (a 95/5 ratio) by two successive evaporations to precipitate the racemate. Such a process on the prebiotic earth could lead to a mechanism by which meteoritic chiral alpha-alkyl amino acids could form solutions with high ee values that were needed for the beginning of biology.

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