Preparation of anion exchanger by amination of acrylic acid grafted polypropylene nonwoven fiber and its ion-exchange property

To develop the polymeric adsorbent that possess anionic exchangeable function, PP-g-AA-Am fibers were prepared by photoinduced grafting of acrylic acid (AA) onto polypropylene (PP) nonwoven fibers and subsequent conversion of carboxyl group in grafted AA to an amine (Am) group by reaction with diethylene triamine (DETA). The amination of grafted AA increased with increase in the degree of grafting, the reaction time and temperature of the chemical modification process. Catalytic effect of metal chlorides such as AlCl3 and FeCl3 on the amination of grafted AA was significant but not essential to lead the amination. FT-IR and solid C-13 NMR data indicate that amine group was introduced into PP-g-AA fiber through amide linkage between grafted AA and DETA. The anion exchange capacity of PP-g-AA-Am fiber increased with increase in the degree of amination, but reached maximum value at about 60% amination of 150% grafted AA. PP-g-AA-Am fiber showed much higher maximum capacity for PO4-P and a similar capacity for NO3-N compared to commercial anion resins. Furthermore, the PP-g-AA-Am fiber also has adsorption ability for cations because of unaminated residual carboxyl group. (c) 2006 Elsevier Inc. All rights reserved.