期刊
INORGANICA CHIMICA ACTA
卷 359, 期 12, 页码 3996-4000出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2006.03.043
关键词
thiol; disulfides; catalysis; iron; nitrilotriacetate
The complexes (cnt)(2)[Fe(nta)Cl-2], where nta = nitrilotriacetate and cnt = Et4N+ or PyH+, catalyze the air oxidation of thiols to disulfides under ambient conditions. Dithiols are converted to linear and cyclic oligomers that differ in their terminal groups as a function of the counterion, cnt. Cysteine ethyl ester was converted to the corresponding cystine diethylester in high yield. (c) 2006 Elsevier B.V. All rights reserved.
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