期刊
JOURNAL OF HETEROCYCLIC CHEMISTRY
卷 43, 期 5, 页码 1319-1326出版社
WILEY
DOI: 10.1002/jhet.5570430526
关键词
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The epoxidation of 2-styrylchromones 2a-h using Jacobsen's Mn(III)[salen] complex I as catalyst is reported for the first time. Several studies were performed using both hydrogen peroxide and iodosylbenzene as oxidants, in order to obtain the alpha,square-epoxy-2-styrylchromones 3a-h regioselectively. Due to the low reactivity of the substrates and the highly unstable character of the formed epoxides, reactions should be interrupted at lower conversions to obtain acceptable yields, especially when hydrogen peroxide is used.
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