期刊
KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 23, 期 5, 页码 761-766出版社
KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/BF02705924
关键词
kinetic analysis; thermal-oxidative decomposition; expandable polystyrene
The kinetics of the thermal-oxidative decomposition of expandable polystyrene (EPS) was studied by a conventional thermogravimetric technique in various concentrations of oxygen from 0 to 21%. A kinetic model that accounts for the effects of oxygen concentration was proposed to describe the thermal-oxidative decomposition of EPS. The thermogravimetric analysis curve and its derivative have been analyzed by using differential and integral methods with modification of the Friedman and Coats-Redfern methods. The activation energy, the pre-exponential factor, and the reaction order for unreacted material and oxygen concentration have been determined. When oxygen was present, the activation energy was reduced significantly.
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