期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 594, 期 2, 页码 80-88出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2006.05.034
关键词
partition coefficient; volume ratio; weak bases; cyclic voltammetry; liquid vertical bar liquid interface
A novel electrochemical approach to the determination of the partition coefficient of neutral weak bases is presented. This determination is based on the measurement of the voltammetric current for the charge transfer across the oil/water interface. Digital simulations and experimental results for monoprotic and polyprotic species have validated this procedure. (c) 2006 Elsevier B.V. All rights reserved.
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