期刊
COORDINATION CHEMISTRY REVIEWS
卷 250, 期 17-18, 页码 2234-2260出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2006.01.026
关键词
molecular materials; crystal engineering; octacyanometalates; magnetic coupling; photomagnetism; cyano bridge; crystal structures
The formation of supramolecular assemblies based on octacyanometalates [M(CN)(8)](3-/4-) (M = Mo, W and Nb) of potential relevance in nanotechnological applications is currently attracting considerable attention. Intensive research in this field resulted in the synthesis and magnetochemical characterization of high-spin polynuclear molecules as well as extended multidimensional coordination networks which behave like molecular or photoinduced magnets. This article discusses the structural and magnetic aspects of the polynuclear systems built by the non-rigid octacyanometalate anionic precursors, from zero-dimensional clusters to three-dimensional frameworks. (c) 2006 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据