期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 12, 期 26, 页码 6829-6840出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200501189
关键词
kinetics; molecular recognition; recognition-mediated reactions; self-replication; supramolecular chemistry
It is envisioned that protocols based on self-replication will emerge as a formidable synthetic apparatus for the production of nanoscale assemblies through molecular structures that are capable of automultiplication with high reaction rates and selectivities. To achieve this goal, a complete understanding of the relationship between molecular structure and replication efficiency is necessary. Rigorous experimental and theoretical analyses of a series of self-complementary scaffolds that are intimately related in a constitutional sense, manufactured through the Diels-Alder reaction of complementary subunits, were undertaken. Experimental and computational methods were employed to map the key determinants that dictate the emergence of self-replicative function, as well as the efficiency, rate and selectivity of the self-replicative processes.
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