期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 59, 期 13, 页码 1477-1482出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970600559591
关键词
crystal structure; lead; isonicotinate
A new coordination polymer [Pb(C5H4NCOO)(2)(H2O)](n) has been prepared by reaction of Pb(NO3)(2) with isonicotinic acid in the presence of equimolar NaOH. Single-crystal X-ray diffraction analysis reveals that the coordination geometry of each lead(II) centre in [Pb(C5H4NCOO)(2)(H2O)](n) is a distorted square antiprism comprised of five O atoms and one N atom from three distinct isonicotinate ligands, and two water molecules. The complex displays a three-dimensional network structure, in which isonicotinate ligands adopt two different bridging coordination modes.
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