期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 691, 期 19, 页码 4153-4158出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2006.06.015
关键词
rhenium complexes; dinitrogen complexes; N,O-ligands; picolinic acid; crystal structures; electrochemistry
A new dinitrogen rhenium(I) complex with a picolinate ligand has been prepared and fully characterized, providing the first example of a genuine N N complex bearing a carboxylate or a N,O-coligand. The Lever electrochemical E-L ligand parameter was estimated for the first time for the picolinate ligand and shows that its carboxylate arm has a net electron-donor character similar to that of chloride, thus stabilizing the trans Re-N-2 bond. (c) 2006 Elsevier B.V. All rights reserved.
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